CR 59:207-228 (2014)  -  DOI: https://doi.org/10.3354/cr01211

ABSTRACT: An integrated chemistry–climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on northern Africa and the Greater Cairo (GC) region. The densely populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjunction with natural sources such as dust, and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average ground-based observations of the daily July maximum nitrogen dioxide (NO₂) are 40 to 60 parts per billion by volume (ppbv) and are about 10 ppbv higher than modeled estimates, likely due to model grid cell resolution, improper boundary layer representation, and poor emissions inventories. Observed July daily maximum ozone concentrations range from 30 ppbv (winter) to 90 ppbv (summer). The model reproduces the seasonal cycle fairly well, but modeled July ozone is underestimated by approximately 10 ppbv and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry–climate model captures the springtime peak aerosol optical depth (AOD) of 0.7 to 1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta; however, the model underestimates this observed AOD peak in fall, as standard emissions inventories underestimate the extent of this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities, specifically NO_x and organic aerosols, are needed to improve air quality simulations in this region.

KEY WORDS: Ozone · Mediterranean · Urban · Air quality